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    • 专利摘要:
    IMPACT RESISTANT MULTIPOLAR POWER CABLE, AND PROCESS FOR THE PRODUCTION OF AN IMPACT RESISTANT MULTIPOLAR POWER CABLE. The present description relates to an impact resistant multipolar power cable (10) comprising a plurality of conductors (1), each core (1) comprising at least one conductive element (3) and an electrical insulation layer (5) in a radially external position for the at least one conductive element (3). The cores (1) are filaments together so as to form an assembled element providing a plurality of interstitial zones (2). An expanded polymeric filler (6) fills the interstitial zones (2) between the plurality of cores (1). An expanded impact resistant layer (7) is at a position radially external to the expanded polymeric filler material (6) and comprises a polymer which differs from the expanded polymeric filler material (6).
    公开号:BR112016006186B1
    申请号:R112016006186-1
    申请日:2013-09-23
    公开日:2021-05-18
    发明作者:Ryan TRUONG；Paul Cinquemani；Andrew Maunder；Chris AVERILL
    申请人:Prysmian S.P.A.；
    IPC主号:
    专利说明:

    FUNDAMENTALS OF THE INVENTION 1. Field of Invention
    [001] This description refers to multipolar power cables, particularly for the transport or distribution of low, medium or high voltage electrical energy, presenting impact resistant properties and a process for its production.
    [002] More particularly, the present description relates to impact resistant multipolar power cables comprising a plurality of filament cores to form an assembled element with interstitial zones between the cores; an expanded polymeric filler that fills the interstitial zones; and an impact resistant, expanded polymeric layer radially external to and in contact with the expanded polymeric filler. 2. Fundamentals
    [003] Within the scope of this description, "low voltage" generally means a voltage less than about 1 kV, "medium voltage" means a voltage between 1 kV and 35 kV, "high voltage" means a voltage greater than 35 kV.
    [004] Electrical cables generally comprise one or more individually insulator-coated conductors and optionally semiconductor polymeric materials and one or more protective coating layers that may also be made of polymeric materials.
    [005] Accidental impacts on a cable, which may occur, for example, during its transportation, placement and operation, can cause structural damage to the cable, including deformation or detachment of insulating and/or semiconductor layers, and the like. This damage can cause variations in the electrical gradient of the insulating coating, with a consequent decrease in the insulating capacity of this coating.
    [006] Commercially available cables, for example, those for transmission or distribution of low or medium or high voltage energy, provide metal armor or shielding capable of withstanding such impacts. The armor/shield can be in the form of ribbons or wires (usually made of steel) or alternatively in the form of a metallic foil (usually made of lead or aluminum). This reinforcement with or without an adherent coating is, in turn, often clad with an outer polymer sheet. An example of such a cable structure is described in U.S. Pat. No. 5,153,381.
    [007] It has been noted that the presence of the aforementioned armor or metal armor, however, has a number of shortcomings. For example, the application of said armature/shield includes one or more additional steps in cable processing. Furthermore, the presence of the metallic armor considerably increases the weight of the cable. In addition, the metallic armor/shield can pose environmental problems since, if it needs to be replaced, a cable constructed in this way is not easy to arrange.
    [008] To produce lighter and more flexible cables, expanded polymeric materials have replaced metallic armor/armors, while still maintaining impact resistance and, at least to a certain degree, flame and chemical agents. For example, a solid interstitial filler superimposed on an expanded polymeric layer can provide excellent impact strength, as described in U.S. Patent No. 7,601,915. However, flexibility and cable weight is sacrificed.
    [009] Alternatively, an expanded polymeric material can fill the interstitial volume between and superimposed on the core elements present in the internal structure of the cable. U.S. Patent No. 6,501,027 describes a power cord comprising a polymeric filler expanded in the interstitial volume between the cores with an outer foil coating. The expanded polymeric filler is obtained from a polymeric material which has, before expansion, a flexural modulus greater than 200 MPa. The polymer is usually expanded during the extrusion phase; this expansion can occur chemically, by means of a compound capable of generating a gas, or it can take place physically, by means of high pressure gas injection directly into the extrusion cylinder. The outer sheet, which is an unexpanded polymeric layer, is subsequently extruded onto the expanded polymeric filler.
    [0010] U.S. Patent No. 7,132,604 describes a handle having a reduced weight and a reduced amount of material extruded into the outer sheet and comprising an expanded polymeric filler and an expanded coating material around the filler. The expanded coating material can be any material that has a tensile strength between 10.0 MPa and 50.0 MPa. The expansion rate of the coating material can be from 5% to 50%. The filler material can be a material based on polyvinylchloride, rubber, EPDM (Ethylene Propylene Thermopolymer) or POE (Polyolefin Elastomer). The filler can be made of expanded material. The expansion rate of the filler can be from 10% to 80%.
    [0011] U.S. Patent No. 7,465,880 teaches that applying an expandable polymeric material to the interstitial zones of a multipole cable is a complex operation that requires special care. An incorrect application of such material within the interstitial zones of the assembled element will result in unacceptable structural irregularities occurring in the cable. The polymeric material that is applied to the interstitial zones by extrusion expands most in the portion of the interstitial zone that has the most space available to expand, and the resulting cross-section of the semi-finished cable has an outer perimeter profile that is substantially three-lobed.
    [0012] To overcome the non-uniform and non-circular expansion of the polymeric filler, US Patent No. 7,465,880 teaches to deposit the filler consisting of expandable polymeric material by coextrusion with a containment layer of unexpanded polymeric material . Optimal mechanical resistance against accidental impact is imparted to the cable of U.S. Patent No. 7,465,880 by arranging a layer of expanded polymeric material in a position radially external to the containment layer.
    [0013] U.S. Patent Application Publication No. 2010/0252299 describes a cable comprising a conductive core, an expanded polymeric filler and an armature layer. A foaming agent can be configured to create voids in the filler. After being extruded onto the conductive core, the filler may have a clamping force applied to its exterior by the armature. The armature is configured to tighten the voids in the fill agent. SUMMARY OF THE INVENTION
    [0014] A need has been realized for a lightweight and flexible multipole power cord, particularly a fire retardant multipole power cord with adequate impact resistance, yet without a containment layer. The use of a containment layer may additionally require an additional expanded polymer layer to provide the desired impact strength, thus adding to the cost, complexity and increased dimensions of the resulting rope.
    [0015] However, Applicants were faced with the problem of manufacturing a cable having an expanded polymeric filler for the interstices and an expanded impact resistant layer, radially external and in contact with the expanded polymeric filler. In particular, Applicants have encountered problems of co-extrusion of these two expanded cable portions, where the expansion of the polymeric filler into the interstices should be as uniform as possible to avoid irregularities in shape and surface that cannot be counterbalanced by the impact resistant layer, which could not play the role of a containment layer as it was expanded.
    [0016] The polymer composition of the filler for the interstices should be different from that of the impact resistant layer. Although both structures should be endowed with significant mechanical strength, the filling agent for the interstices plays a major role in providing flexibility to the cable; consequently, its polymeric composition should be less rigid than that of the impact resistant layer which should withstand the main effort in the case of mechanical shock. In addition, when the two layers are made of the same material, problems arise at their interface due to undesirable adhesion between the layers.
    [0017] It has been found that, by the proper selection of expandable polymeric materials, the filler for the interstices between and on the core elements can be coextruded with the impact resistant layer while maintaining the concentricity of impact resistance in expansion .
    [0018] Thus, one aspect of the present description provides an impact resistant multipolar power cable comprising: a) a plurality of cores, each core comprising at least one conductive element and an electrical insulation layer in a radially external position to the at least a conductive element, the cores being filaments together to form an assembled element providing a plurality of interstitial zones; b) an expanded polymeric filler filling the interstitial zones, and comprising a polymer with a Shore D hardness in the range of 30 to 70, a flexural modulus of 50 MPa to 1500 MPa at 23°C, and an LOI value of 27 to 95% before expansion; c) an impact resistant layer in a radially outward position to and in contact with the agent of expanded polymeric filler, wherein the layer comprises an expanded polymer which differs from the filler polymer and has, prior to expansion, a flexural modulus greater than that of the powder. limer for the filling material; and d) a solid polymeric coating surrounding the impact resistant layer.
    [0019] In another aspect, the present description provides a process for producing an impact resistant multipolar power cable comprising a plurality of cores, each core comprising at least one conductive element and an electrical insulating layer in a position radially external to the at least one conductive element, the cores being filaments together so as to form an assembled element providing a plurality of interstitial zones; an expanded polymeric filler filling the interstitial zones; an impact resistant layer in a radially outward position to and in contact with the expanded polymeric filler; and a solid polymeric coating surrounding the impact resistant layer, the process comprising a) providing an extruder with a first polymeric material with a Shore D hardness in the range of 30 to 70, a flexion modulus of 50 MPa to 1500 MPa at 23° C, and an LOI value of 27 to 95% for producing the expanded polymeric filler; b) providing an extruder with a second polymer material for producing the impact resistant layer, said second polymer of a flexural modulus greater than that of the first polymer c) adding a foaming agent for the first and second polymer material, the foaming agent for at least the first polymer comprising thermally expandable microspheres; d) triggering the foaming agent of the first and second polymer material to expand the polymer in question; e) co-extruding the first and second polymer material expanded to form the polymeric filler by filling the zones in the interstitials and the impact resistant layer; and f) extruding a solid polymeric coating around the impact resistant layer.
    [0020] A balance of Shore D hardness, flexural modulus and LOI properties for the expanded polymeric filler polymer has been found to be effective in providing the rope with advantageous properties. Higher Shore D hardness and flexural modulus improve the impact strength of the total rope. However, if the impact resistance is too high, the cable will be too rigid, not as flexible as desired. By expanding the polymer, the cable is more flexible. As used herein and in the claims, Shore D hardness, flexural modulus and LOI refer to properties of the polymer before it is expanded. As used herein, and unless otherwise specified, the term "LOI" refers to limited oxygen index, that is, the minimum concentration of oxygen, expressed as a percentage that will support combustion of a polymer. As used herein and in the claims, Shore D hardness, flexural modulus and LOI refer to properties as determined by ASTM D2240, ASTM D790 and ASTM D2863, respectively.
    [0021] As used herein, an interstitial zone is the volume enclosed between two filament cores and the cylinder enveloping the filament cores.
    [0022] As used herein, an impact resistant layer means a layer of cable providing the cable with the ability to suffer zero or negligible damage under impact, such that the performance of the cable is not compromised or reduced.
    [0023] It has been found that by using thermally expandable microspheres as a foaming agent for at least the polymeric filler for the interstices, the filler can be co-extruded with an expandable polymeric layer while maintaining its concentricity and strength impact on expansion.
    [0024] Then, in one embodiment, at least the polymeric filler for the interstices contains expanded microspheres. In yet another embodiment, the foaming agent added to the second polymer material comprises thermally expandable microspheres and the impact resistant layer of the cable also comprises expanded microspheres. The use of microspheres allows for a better control of the expansion, and, as a consequence, a better roundness of the final cable.
    [0025] Advantageously, the polymer material for the interstitial zone filler (first polymer material) is selected from polyvinyl chloride (PVC), polyvinylidene fluoride (PVDF), vulcanized thermoplastics (TPV), flame retardant polypropylene and thermoplastic olefins (TPO). Suitable TPOs for the present description include, but are not limited to, low crystalline polypropylene (having a melting enthalpy lower than 40 J/g) and alpha olefin polymer. In one embodiment, the polymer material for the interstitial zone filler is selected from polyvinylchloride and polyvinylidene fluoride.
    [0026] As used herein, and unless otherwise specified, the term "vulcanized thermoplastic" or TPV refers to a class of thermoplastic elastomer (TPE) that contains a crosslinked rubber phase dispersed within a thermoplastic polymer phase. . In one embodiment, the TPV suitable for the cable filler of the invention contains an amount of crosslinked rubber phase from 10% by weight to 60% by weight with respect to the weight of the polymer.
    [0027] As used herein, and unless otherwise specified, the term "thermoplastic elastomer" or TPE refers to a class of copolymers or a physical blend of polymers (usually a plastic and a rubber) consisting of materials with both thermoplastic and elastomeric properties.
    [0028] The polymer material of the interstitial filler can achieve a degree of expansion of 15 to 200%, such as 25 to 100%. A limited degree of expansion of the polymeric material of the interstitial filler leads to maintaining the circularity of the cable, while providing the cable with the sought-after flexibility and reduced weight.
    [0029] In one embodiment, the expandable polymeric material of the interstitial filler extends beyond and overlaps the plurality of cores and interstitial zones, such that a circular ring surrounds the plurality of cores and interstitial zones. This extension of the interstitial filler over the core (also referred to as the annular layer) can have a thickness of about 1 mm to 6 mm. Greater thickness of this circular ring can be predicted depending on the cable path.
    [0030] Advantageously, the polymer material for the impact resistant layer (second polymer material) is selected from polyvinylidene fluoride (PVDF), flame retardant polypropylene (PP) and polyethylene (PE). In one embodiment, the polymer material for the impact resistant layer is selected from polyvinylidene fluoride and polyprolylene. Notably, PVC and PVDF are flame retardant polymers. Polypropylene and polyethylene are given flame retardant properties by the addition of organic flame retardant compounds, for example brominated flame retardants such as decabromodiphenyl ether, propylene dibromo styrene, hexabromocyclododecane or tetrabromobisphenol A.
    [0031] In at least one embodiment, one or more opening cords are arranged in the interstitial areas. The one or more opening cords can be made of a material chosen, for example, from fiberglass and aramid thread. BRIEF DESCRIPTION OF THE DRAWINGS
    [0032] Additional details will be illustrated in the following attached drawings, in which: Figure 1 shows, in cross section, one modality of a cable, according to the present description; Figure 2 shows, in cross section, another modality of a cable, in accordance with the present description. DETAILED DESCRIPTION
    [0033] The power cables of the present description are multipole cables. For purposes of the present description, the term "multicore cable" means a cable provided with at least one pair of "cores". For example, if the multi-core cable has three cores, the cable is known as a "three-core cable".
    [0034] As used herein, and unless otherwise specified, the term "core" refers to a conductive element (typically consisting of copper or aluminum in the form of wires or rods), electrical insulation, and optionally, minus one semiconductor layer, typically provided in radially outward position with respect to the electrically insulating layer. A second (inner) semiconductor layer may be present and typically provided between the electrically insulating layer and the conductive element. A wire mesh, in the form of wires or braided or conductive metal tapes can be provided as the outermost core layer.
    [0035] Figure 1 illustrates an sketched view of a cross-section of a three-pole cable, according to an embodiment of the present description. This cable (10) contains three cores (1) and three interstitial zones (2). Each core (1) comprises a conductive element (3), an inner semiconductor layer (4a), an electrically insulating layer (5) which can be crosslinked or not, and an outer semiconductor layer (4b).
    [0036] The three cores (1) are filaments together forming interstitial zones (2) defined as the spaces between the cores (1) and the cylinder enveloping such cores. The outer perimeter profile of the cross section of the filament cores is, in this case, three-lobed as there are three cores.
    [0037] An expanded polymeric filler (6) fills the interstitial zones (2) interdisposed between the cores (1). The expanded polymeric filler (6) extends beyond and overlaps the filamentous cores (1) and interstitial zones (2) as defined by the annular region (6a).
    [0038] Alternatively, as shown in Figure 2, the expanded polymeric filler (6) only fills the interstitial zones (2) interdisposed between the filament cores (1). This does not form any significant annular layer superimposed on the interstitial zones (2) and filamentous cores (1).
    [0039] In order to give a multipole cable a suitably substantially circular cross section, the expanded polymeric filler expands to fill and optionally overlaps the interstitial zones and cores.
    [0040] The expanded polymeric filler (6, 6a) is surrounded by and is in contact with an expanded impact resistant layer (7).
    [0041] As used herein, and unless otherwise specified, the term "expanded" refers to a polymer in which the "vacant" volume percentage is typically greater than 10% of the total volume of said polymer. As used herein, and unless otherwise specified, the term "vacant" refers to space not occupied by the polymer but by gas or air. An unexpanded polymer is also referred to as a "solid".
    [0042] As used herein, and unless otherwise specified, the term "degree of expansion" refers to the percentage of free space in an expanded polymer. The degree of expansion of an expanded polymer can be defined according to the following equation: G = (do/de - 1) x 100 where d0 indicates the density of the unexpanded polymer and de represents the measured bulk density of the expanded polymer.
    [0043] Expanded polymeric filler (6) and expanded impact resistant layer (7) were selected to meet the requirements discussed above. The cable (10) does not have a solid containment layer in contact with the expanded polymeric filler (6) and is capable of providing the filler with the desired roundness.
    [0044] The cable (10) of Figures 1 and 2 is additionally provided with an optional layer of metal (8) (for example, aluminum or copper) or metal/polymer composite (for example, aluminum/polyethylene) with overlapping edges ( not shown) and an adhesive coating (not shown). Layer (8) can act as a barrier to water or moisture, is typically 0.01 mm to 1 mm thick and has negligible or no performance as an impact resistant layer.
    [0045] A polymeric coating (9) is provided, typically consisting of PE, PVC or chlorinated polyethylene, optionally added with anti-UV additives, such as by extrusion, as the outermost cable layer. The polymeric coating typically has a thickness of 1.0mm to 3.0mm or more, depending on the cable size.
    [0046] Optionally, the cable (10) comprises a chemical barrier (not shown) in the form of a polymer layer provided in radially internal position with respect to the polymeric coating (9) and in radially external position with respect to the impact resistant layer expanded (7). For example, the chemical barrier can be as described in U.S. Patent No. 7,601,915. The barrier may comprise at least one polyamide and copolymers thereof, such as a polyamide/polyolefin blend, or TPE, and have a typical thickness of 0.5mm to 1.3mm. In at least one modality, when the impact resistant layer is made of PVDF, it can also act as a chemical barrier layer, without changing the thickness, thus providing a cable with a reduced diameter. In another embodiment, the chemical barrier layer is a polyimide.
    [0047] Expansion to form an expanded polymer filler and the impact resistant layer takes place during extrusion, more specifically before the polymeric material passes through the extrusion die. The expansion of the impact resistant layer can be by chemical agents, for example, by adding the polymer composition of a suitable blowing agent, which is capable of producing a gas under specific conditions of temperature and pressure. Examples of suitable blowing agents are azodicarbanide, paratoluene sulfonylhydrazide, mixtures of organic acids (eg citric acids) with carbonates and/or bicarbonates (eg sodium bicarbonate) and the like.
    [0048] In another embodiment, expansion to form an expanded impact resistant layer can take place due to microspheres that can be chosen from thermally expandable microspheres. Expansion of the polymer filler is accomplished by thermally expandable microspheres. Thermally expandable microspheres are particles comprising a shell (typically thermoplastic) and a low boiling organic solvent encapsulated therein. With the increased temperature, the organic solvent vaporizes into a gas that expands to produce high internal pressures. At the same time, the shell material softens with heat, such that the entire particle expands under the internal pressure to form large bubbles. The microspheres are relatively stable and do not shrink after cooling. A suitable example of a thermally expandable microsphere is the commercial product sold under the name Expancel® from Eka Chemicals.
    [0049] The polymer material is substantially fully expanded while still in the transverse head of the extruder and no significant expansion of the material occurs after it exits the extrusion die. This allows for controlled expansion with a circular cross section.
    [0050] The use of thermally expandable microsphere as a foaming agent has been found to be particularly suitable for expanding the polymeric filler, although the choice of foaming agent for the impact resistant layer is less critical. In one embodiment, thermally expandable microspheres are used in both polymeric filler and impact resistant layer.
    [0051] According to the present description, the polymer suitable for the interstitial filler has a Shore D hardness ranging from 30 to 60, a flexural modulus (at 23°C according to ASTM D 790) ranging from 50 MPa to 1500 MPa, and a limit oxygen index (LOI) ranging from about 25% to 95%. As polymer properties may differ as expanded or unexpanded, polymer material properties are measured prior to expansion.
    [0052] Examples of suitable polymer for the interstitial filler include, but are not limited to, thermoplastic polymers selected, for example, from vulcanized thermoplastics (TPV), thermoplastic olefins (TPO), flame retardant polypropylene, polyvinyl chloride (PVC), polyvinylidene fluoride (PVDF) and combinations thereof. Flame retardant polypropylene comprises halogenated (eg brominated) flame retardant organic components added as already mentioned above. Thermoplastic polyurethane elastomers and thermoplastic polyester are unsuitable as the expandable material for the interstitial filler and impact resistant cable layer of the invention. Thermoplastic polyurethane and some thermoplastic polyester elastomers demonstrated poor flame retardancy, while other thermoplastic polyester elastomers were considered too difficult to be adequately expanded.
    [0053] A non-limiting example of a TPV is Santoprene™ available from Exxon Mobil. Non-limiting examples of TPOs include polymers that are available from DuPont, Heraflex® TPC-ET from RadiciPlastics.
    [0054] As used herein, and unless otherwise specified, the term "containment layer" refers to an unexpanded layer, whether polymeric or otherwise, that functions to maintain the concentricity of the polymer filler expanded around cores of a multicore cable. Without being limited to a particular theory, expanded layers are unable to maintain the concentricity of an expanded polymer filler.
    [0055] In at least one embodiment, the polymer suitable for the interstitial filler achieves a degree of expansion ranging from 15% to 200%, for example, from 25% to 100%. The expanded polymer filler expands to fill the interstitial zones and optionally to overlap and protect the various cores. In at least one embodiment, the filler overlaps the various cores and interstitial zones with a thickness of about 0.5 mm to about 6 mm, producing a substantially circular cross section.
    [0056] According to the present description, the impact resistant layer is not a containment layer, but an expanded polymer layer. The polymer suitable for the impact resistant layer has a higher flexural modulus than the polymer in the interstitial filler. The flexural modulus of the impact resistant layer can range from 500 to 2500 MPa.
    [0057] Examples of the polymer in the impact resistant layer include, but are not limited to, polyvinylidene fluoride (PVDF), polypropylene (PP), polyethylene (PE) and mixtures thereof. In one embodiment, the polymer is an ethylene-propylene copolymer.
    [0058] A non-limiting example of polyethylene (PE) is low density PE (LDPE), medium density PE (MDPE), high density PE (HDPE), linear low density PE (LLDPE), ultra low density polyethylene (ULDPE).
    [0059] In at least one embodiment, the polymer suitable for the impact resistant layer achieves a degree of expansion ranging from 20% to 100%, for example, from 20% to 50%.
    [0060] In at least one embodiment, the expanded polymer filler and the impact resistant layer are made of different polymeric materials. In particular, the material for the expanded impact resistant layer has a higher flexural modulus than that of the interstitial filler material.
    [0061] Cables in accordance with the present description can be produced by any well-known manufacturing methods for multicore cables. The polymeric filler and impact resistant layer are provided to surround the filament rope cores by co-extrusion or parallel extrusion.
    [0062] Preferably, the co-extrusion of the interstitial filler and impact-resistant layer materials - featuring different processing temperatures - is performed in a single transverse extrusion head by pressure extrusion of the interstitial filler and extrusion finisher for the impact resistant layer.
    [0063] Illustrative, non-limiting examples are presented below in order to describe the present description in further detail. EXAMPLES Cable Preparation with Expanded Filling Agent
    [0064] A series of three-pole cables according to the present description, as well as comparative ones were constructed. These cables are identified in the following text by the letters A to R and are detailed in Table 1. For each of the cables A to R, a triple core was insulated with cross-linked polyethylene (XLPE). The construction of the cable is specified in Table 1.
    [0065] Comparative cables E and F were prepared based on known cable designs. Cable E has no filler, just an impact resistant layer in the form of metallic armor (Mylar tape surrounded by welded aluminum armor) surrounded by a PVC coating, extruded over the cable core to complete the construction. Cable F has an impact resistant layer in the form of corrugated aluminum armor and a full PVC jacket, extruded over the cable core to complete the construction.



    [0066] In cables A, M and Q, the impact resistant layer also works as a chemical barrier.
    [0067] The outer layer present in Q and S cables is a coextruded layer with filler to provide a better surface on the filler. The outer layer does not provide a containment function.
    [0068] The co-extrusion of the filler/impact resistant layer of the comparative rope S was problematic due to difficulties in controlling the dimension especially in terms of cross section circularity and in obtaining a smooth surface. Also the cable did not pass the impact resistance test.
    [0069] In order to evaluate the multicore cables prepared in Table 1, impact, flame, flexibility and crush tests were conducted.
    [0070] Impact tests. The effect of impacts on a cable was evaluated by an impact test based on the IEC61901 standard (1st edition, 2005-07). The effects of an impact to various forces (J) were evaluated by measuring the depth of damage (mm). The cables have been subjected to impact levels from 25 J to 70 J or more severe conditions (from 150 J to 300 J) depending on their intended use. The depth of damage gives an indication of the degree of protection provided by the impact resistant layer. Tables 2a and 2b establish the values of the various analyzed energy levels, depth of damage (mm) measured for the AF and MQ samples.

    [0071] This test shows that cables according to the invention resisted impact in a way at least comparable to cable with E and F armor.
    [0072] Other tests: Flexibility and the effects of flame and crushing on certain multipole cables were also evaluated. The flame test is a pass/fail test that follows the IEEE-1202 standard for 60 inches (about 1.5 m) in length, the flexibility test is a three-point bend test, recorded at 1% of modulus. drier in accordance with ASTM D-790. The crush test applies the UL-1569 5340N (1200 lbf) configuration procedure as the minimum load, and the table reports the maximum load supported by the cables. Table 3 presents the values for these test results. Table 3: Flame, Flexibility and Crush Test Results

    [0073] This test shows that the cables of the invention performed favorably when compared to cables of the prior art. Its crush resistance meets standard requirements and is accompanied by remarkably improved flexibility and flame-bearing ability.
    [0074] The cables of the invention provide a solution for a cable that is light, flexible, impact resistant, crush resistant, flame resistant and resistant to chemicals.
    权利要求:
    Claims (13)
    [0001]
    1. Impact resistant multipolar power cable, comprising a plurality of cores (1), each core comprising at least one conductive element (3) and an electrically insulating layer (5) in a position radially external to the at least one conductive element. (3), the cores (1) being filaments together to form an assembled element providing a plurality of interstitial zones (2); characterized in that it further comprises: a) an expanded polymeric filler (6) filling the interstitial zones (2), and comprising a first polymer material with a Shore D hardness in the range of 30 to 70, a flexural modulus of 50 MPa to 1500 MPa at 23°C, and an LOI value of 27 to 95% prior to expansion, the expanded polymeric filler (6) containing expanded microspheres; b) an impact resistant layer (7) in a radially outward position to and in contact with the expanded polymeric filler (6), wherein the bed The impact resistant (7) comprises a second expanded polymer material, which differs from the first material by the expanded polymeric filler (6) and has, before expansion, a higher flexural modulus than the first polymer material. for the expanded polymeric filler (6); and c) a solid polymeric coating (9) surrounding the impact resistant layer (7).
    [0002]
    2. Cable according to claim 1, characterized in that the expanded polymeric filler (6) comprises the first polymer material chosen from vulcanized thermoplastics (TPV), thermoplastic olefins (TPO), flame retardant polypropylene , polyvinyl chloride (PVC), polyvinylidene fluoride (PVDF) and combinations thereof.
    [0003]
    3. Cable according to claim 1, characterized in that the expanded polymeric filler (6) has a degree of expansion in the range of 15% to 200%.
    [0004]
    4. Cable according to claim 3, characterized in that the expanded polymeric filler (6) has a degree of expansion in the range of 25% to 100%.
    [0005]
    5. Cable according to claim 1, characterized in that the impact resistant layer (7) comprises a second polymer material chosen from polyvinylidene fluoride (PVDF), polypropylene (PP), polyethylene (PE) and mixtures thereof.
    [0006]
    6. Cable according to claim 1, characterized in that the impact resistant layer (7) has a degree of expansion in the range of 20% to 200%.
    [0007]
    7. Cable according to claim 6, characterized in that the impact resistant layer (7) has a degree of expansion in the range of 20% to 50%.
    [0008]
    8. Cable according to claim 1, characterized in that the impact resistant layer (7) contains expanded microspheres.
    [0009]
    9. Cable according to claim 1, characterized in that it additionally comprises a chemical barrier layer.
    [0010]
    10. Cable according to claim 1, characterized in that the expanded polymeric filler (6) fills the interstitial zones (2) and forms an annular layer (6a) overlaying the interstitial zones (2) and the cores in filaments (1).
    [0011]
    11. Cable according to claim 10, characterized in that the annular layer (6a) has a thickness of 1 mm to 6 mm.
    [0012]
    12. Process for producing an impact resistant multipolar power cable comprising a plurality of cores (1), each core comprising at least one conductive element (3) and an electrical insulating layer (5) in a position radially external to the at least one conductive element (3), the cores (1) being filaments together to form an assembled element providing a plurality of interstitial zones (2); an expanded polymeric filler (6) filling the interstitial zones (2); an impact resistant layer (7) in a radially outward position to and in contact with the expanded polymeric filler (6); and a solid polymeric coating (9) surrounding the impact resistant layer (7), the process characterized in that it comprises a) providing an extruder with a first polymer material with a Shore D hardness in the range of 30 to 70, a modulus of flexion of 50 MPa to 1500 MPa at 23°C, and an LOI value of 27 to 95% to produce the expanded polymeric filler (6); b) providing an extruder with a second polymer material for the production of the layer resistant to impact (7), said second polymer material having a flexural modulus greater than that of the first polymer material; c) adding a foaming agent to the first and second polymer materials, the foaming agent foam for at least the first polymer material being thermally expandable microspheres; d) actuating the foaming agent of the first and second polymer materials to expand the relevant first and second polymer materials; e) coextruding the first and sec second expanded polymer materials to form the polymeric filler (6) filling the interstitial zones (2) and the impact resistant layer (7); and f) extruding a solid polymeric coating (9) around the impact resistant layer (7).
    [0013]
    13. Process according to claim 12, characterized in that the foaming agent for the second polymer material comprises thermally expandable microspheres.
    类似技术:
    公开号 | 公开日 | 专利标题
    BR112016006186B1|2021-05-18|Impact resistant multi-pole power cord, and process for producing an impact resistant multi-pole power cord
    ES2448571T3|2014-03-14|Power cable with expanded polymer layers
    ES2178223T5|2009-05-18|CABLE WITH IMPACT RESISTANT COATING.
    US8916776B2|2014-12-23|Cable having expanded, strippable jacket
    CA2449023C|2011-09-27|Optical cable provided with a mechanically resistant covering
    ES2663329T3|2018-04-12|Electrical cables with resistance elements
    US9520210B1|2016-12-13|Shielded twisted pair communication cables
    ES2278709T3|2007-08-16|CABLE WITH AN EXTRUDED EXTERNAL COVER AND METHOD OF MANUFACTURE OF THE CABLE.
    BG64658B1|2005-10-31|Cable with impact-resistant coating
    AU2002314115B2|2007-02-15|Optical cable provided with a mechanically resistant covering
    BR112017019444B1|2022-01-11|MULTI-PHASE POWER CABLE
    US9442263B1|2016-09-13|Cable components formed with a thermoplastic elastomer as a nucleating agent
    US10026522B1|2018-07-17|Flame retardant insulation material for use in a plenum cable
    US20190043643A1|2019-02-07|Electrical lead
    KR20110104228A|2011-09-22|High strength cable for ship
    同族专利:
    公开号 | 公开日
    EP3050064B1|2017-11-08|
    NZ719343A|2019-02-22|
    EP3050064A1|2016-08-03|
    US20160233007A1|2016-08-11|
    AU2013400927B2|2018-10-25|
    RU2016115550A|2017-10-30|
    CA2924618A1|2015-03-26|
    NO3050064T3|2018-04-07|
    WO2015040448A1|2015-03-26|
    DK3050064T3|2018-02-05|
    CA2924618C|2020-10-13|
    BR112016006186A2|2017-08-01|
    RU2638172C2|2017-12-12|
    ES2658220T3|2018-03-08|
    CN105849826B|2017-12-12|
    US9947438B2|2018-04-17|
    AU2013400927A1|2016-04-07|
    CN105849826A|2016-08-10|
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    法律状态:
    2020-03-03| B06U| Preliminary requirement: requests with searches performed by other patent offices: procedure suspended [chapter 6.21 patent gazette]|
    2020-11-03| B06A| Notification to applicant to reply to the report for non-patentability or inadequacy of the application [chapter 6.1 patent gazette]|
    2021-03-09| B09A| Decision: intention to grant [chapter 9.1 patent gazette]|
    2021-05-18| B16A| Patent or certificate of addition of invention granted|Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 23/09/2013, OBSERVADAS AS CONDICOES LEGAIS. |
    优先权:
    申请号 | 申请日 | 专利标题
    PCT/IB2013/002426|WO2015040448A1|2013-09-23|2013-09-23|Lightweight and flexible impact resistant power cable and process for producing it|
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